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In a nice quality-of-life improvement for the Pixel Watch and Wear OS, Google has introduced an extra step before the Find My Phone ring activates.
Restart the iPhone. The first step in troubleshooting any device is to restart it. A restart can fix many glitches.
Check your volume settings. You may have several sliders for volume control for your ring volume, media volume, etc. Be sure to adjust the Ring volume slider.